Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes
نویسندگان
چکیده
منابع مشابه
Synthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia.
A potentially useful trianionic ligand for the reduction of dinitrogen catalytically by molybdenum complexes is one in which one of the arms in a [(RNCH(2)CH(2))(3)N](3-) ligand is replaced by a 2-mesitylpyrrolyl-alpha-methyl arm, that is, [(RNCH(2)CH(2))(2)NCH(2)(2-MesitylPyrrolyl)](3-) (R = C(6)F(5), 3,5-Me(2)C(6)H(3), or 3,5-t-Bu(2)C(6)H(3)). Compounds have been prepared that contain the lig...
متن کاملCatalytic reduction of dinitrogen to ammonia at a single molybdenum center.
Since our discovery of the catalytic reduction of dinitrogen to ammonia at a single molybdenum center, we have embarked on a variety of studies designed to further understand this complex reaction cycle. These include studies of both individual reaction steps and of ligand variations. An important step in the reaction sequence is exchange of ammonia for dinitrogen in neutral molybdenum(III) com...
متن کاملSYNTHESES AND STUDIES OF MOLYBDENUM AND TUNGSTEN COMPLEXES FOR DINITROGEN REDUCTION By JIA
A series of monopyrroletriamine ligands [Arpyr(Ar’)2]H3 of the form ArC4H2NHCH2N(CH2CH2NHAr’)2 (Ar = 2,4,6-mesityl (Mes), 2,4,6-triisopropylphenyl (TRIP); Ar’ = C6F5, 2-tolyl (o-tol), naphthyl, 3,5-(2,4,6-triisopropylphenyl)phenyl (HIPT), 3,5dimethylphenyl, 3,5-di-tert-butylphenyl were synthesized. [Mespyr(C6F5)2]MoCl, ([Mespyr(C6F5)2]Mo = MesitylC4H2NCH2N(CH2CH2NC6F5)2) was prepared by reactio...
متن کاملCatalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
Synthesis and reactivity of iron-dinitrogen complexes have been extensively studied, because the iron atom plays an important role in the industrial and biological nitrogen fixation. As a result, iron-catalyzed reduction of molecular dinitrogen into ammonia has recently been achieved. Here we show that an iron-dinitrogen complex bearing an anionic PNP-pincer ligand works as an effective catalys...
متن کاملSynthesis of [(DPPNCH2CH2)3N]3- molybdenum complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and studies relevant to catalytic reduction of dinitrogen.
Molybdenum complexes that contain a new TREN-based ligand [(3,5-(2,5-diisopropyl-pyrrolyl)(2)C(6)H(3)NCH(2)CH(2))(3)N](3-) ([DPPN(3)N](3-)) that are relevant to the catalytic reduction of dinitrogen have been prepared. They are [Bu(4)N]{[DPPN(3)N]MoN(2)}, [DPPN(3)N]MoN(2), [DPPN(3)N]MoN=NH, {[DPPN(3)N]MoN=NH(2)}[BAr(f)(4)], [DPPN(3)N]Mo[triple bond]N, {[DPPN(3)N]Mo[triple bond]NH}[BAr(f)(4)], a...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2017
ISSN: 0002-7863,1520-5126
DOI: 10.1021/jacs.7b04800